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A comprehensive classification of alloying behavior for 813 binary alloy systems consisting of transition and lanthanide metals. [12] "Impressively, the classification by the miscibility map yields a robust validation on the capability of the well-known Miedema’s theory (95% agreement) and shows good agreement with the HTFP method (90% ...
Bivariate analysis is one of the simplest forms of quantitative (statistical) analysis. [1] It involves the analysis of two variables (often denoted as X, Y), for the purpose of determining the empirical relationship between them. [1] Bivariate analysis can be helpful in testing simple hypotheses of association.
The binary Helmholtz free energy contains different terms that are taking into account various intermolecular forces that can exist based on the inherent of the two target components. Such models are developed for natural gas components through GERG-2008 thermodynamic model and EOS-CGfor the humid and combustion gas-like mixtures.
Glass transitions may occur as the temperature of an amorphous solid is increased. These transitions appear as a step in the baseline of the recorded DSC signal. This is due to the sample undergoing a change in heat capacity; no formal phase change occurs. [15] [17] As the temperature increases, an amorphous solid will become less viscous. At ...
Polymers represent another large area in which thermal analysis finds strong applications. Thermoplastic polymers are commonly found in everyday packaging and household items, but for the analysis of the raw materials, effects of the many additive used (including stabilisers and colours) and fine-tuning of the moulding or extrusion processing used can be achieved by using differential scanning ...
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
In statistics, the phi coefficient (or mean square contingency coefficient and denoted by φ or r φ) is a measure of association for two binary variables.. In machine learning, it is known as the Matthews correlation coefficient (MCC) and used as a measure of the quality of binary (two-class) classifications, introduced by biochemist Brian W. Matthews in 1975.