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Dimethylformamide, DMF is an organic compound with the chemical formula H C O N(CH 3) 2.Its structure is HC(=O)−N(−CH 3) 2.Commonly abbreviated as DMF (although this initialism is sometimes used for dimethylfuran, or dimethyl fumarate), this colourless liquid is miscible with water and the majority of organic liquids.
HATU (Hexafluorophosphate Azabenzotriazole Tetramethyl Uronium) is a reagent used in peptide coupling chemistry to generate an active ester from a carboxylic acid. HATU is used along with Hünig's base (N,N-diisopropylethylamine), or triethylamine to form amide bonds. Typically DMF is used as solvent, although other polar aprotic solvents can ...
The Vilsmeier reagent is an organic compound with the formula [(CH 3) 2 NCHCl]Cl. It is a salt consisting of the N,N-dimethyliminium cation ([(CH 3) 2 N=CHCl] +) and chloride anion. Depending on the particular reaction, the anion can vary. In typical POCl 3-based reactions, the anion is PO 2 Cl 2 −.
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N-Methylformamide (NMF) is a colorless, nearly odorless, organic compound and secondary amide with molecular formula CH 3 NHCHO, which is a liquid at room temperature. NMF is mainly used as a reagent in various organic syntheses with limited applications as a highly polar solvent.
Dihydrolevoglucosenone is considered a "green" replacement for DMF. [5] Several standard reactions of organic chemistry, e.g. Menshutkin reaction, [5] Sonogashira coupling, [18] Suzuki-Miyaura coupling [19] and the production of ureas [20] have been carried out in dihydrolevoglucosenone. Formation of ureas using dihydrolevoglucosenone as a solvent
The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran, are its increased stability and higher solubility. [1] BMS is commercially available at much higher concentrations than its tetrahydrofuran counterpart (10 M ) and does not require sodium borohydride as a stabilizer , which could result in undesired side reactions ...
N-Formylpiperidine is an organic compound with the formula C 6 H 11 NO. It is the amide of formic acid and piperidine.It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide (DMF). [1]