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Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH 2) 4 O. The compound is classified as heterocyclic compound , specifically a cyclic ether . It is a colorless, water- miscible organic liquid with low viscosity .
This page provides supplementary chemical data on tetrahydrofuran. Material Safety Data Sheet ... 50: 60: 66 log 10 Tetrahydrofuran vapor pressure. Uses formula: ...
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It is dissimilar vs ethers such as tetrahydrofuran. Like enol ethers, 2,5-disubstituted furans are susceptible to hydrolysis to reversibly give 1,4-diketones. Furan serves as a diene in Diels–Alder reactions with electron-deficient dienophiles such as ethyl ( E )-3-nitroacrylate. [ 15 ]
2,2,5,5-tetramethyltetrahydrofuran (TMTHF) or 2,2,5,5-tetramethyloxolane (TMO) is a heterocyclic compound with the formula C 8 H 16 O, or (CH 3) 2 (C(CH 2) 2 OC)(CH 3) 2.It can be seen as derivative of tetrahydrofuran (oxolane) with four methyl groups replacing four hydrogen atoms on each of the carbon atoms in the ring that are adjacent to the oxygen.
For example, tetrahydrofuran-3-one (3-ketotetrahydrofuran) [12] and 3-aminotetrahydrofuran [13] have been synthesized from 3-hydroxytetrahydrofuran and used in pharmaceutical syntheses. Additionally, additive amounts (0.05-0.15 weight %) of the nitrate ester manufactured by sulfuric acid - nitric acid nitration of 3-hydoxytetrahydrofuran have ...
The median lethal dose is high, 650–900 mg/kg (oral, dogs), consistent with its pervasiveness in foods. [ 4 ] The Occupational Safety and Health Administration has set a permissible exposure limit for furfural at 5 ppm over an eight-hour time-weighted average (TWA), and also designates furfural as a risk for skin absorption.
It is produced by polymerization of tetrahydrofuran as well as 1,4-butanediol. The product is commercially available as polymers of low average molecular weights , between 250 and 3000 daltons . In this form it is a white waxy solid that melts between 20 and 30 °C.