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Oxidation of 1-methylcyclohexene catalyzed by cytochrome P450 yields a 2:1 mixture of hydroxylation to epoxidation products. [4] The stereochemistry of hydroformylation has been examined using 1-methylcyclohexene. The main product has the formyl group on the less substituted alkene-carbon, trans with respect to the methyl substituent.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid: 298.9 44 ...
Most methylcyclohexane is extracted from petroleum but it can be also produced by catalytic hydrogenation of toluene: CH 3 C 6 H 5 + 3 H 2 → CH 3 C 6 H 11. The hydrocarbon is a minor component of automobile fuel, with its share in US gasoline varying between 0.3 and 1.7% in early 1990s [10] and 0.1 to 1% in 2011. [11]
Methylcyclohexene can refer to any of three compounds: 1-Methylcyclohexene; 3-Methylcyclohexene; 4-Methylcyclohexene This page was last edited on 18 November ...
Boiling point 102 to 103 °C (216 to 217 °F; 375 to 376 K) Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Group → 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18; ↓ Period 1: H 2 20.271 K (−252.879 °C) He 4.222 K (−268.928 °C) 2: Li 1603 K (1330 °C) Be 2742 K ...
It then appears that the reaction proceeds mainly by a trans mechanism and, following the Zaitsev rule, 1-methylcyclohexene is preferentially formed in the early stages of the reaction. Indeed, if only about 10% of the total distillate is collected as the first fraction, one finds that the alkene is about 93% l-methylcyclohexene: at the end of ...