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Representative aromatic amines Aromatic ring Name of parent amines Example benzene: aniline: substituted anilines: phenylenediamines: the antioxidant p-phenylenediamine: toluene: toluidines: the pharmaceutical prilocain: diaminotoluenes: the hair dye ingredient 2,5-diaminotoluene: naphthalene: naphthylamines: the dyes Congo red and Prodan ...
One of the most relevant applications of the substance is the synthesis of 3-(diethylamino)phenol, key intermediate for the preparation of several fluorescent dyes (e.g., rhodamine B). Other uses for the compound include hair dye colorants and stabilizers for chlorine-containing thermoplastics. [4]
4-Aminobiphenyl (4-ABP) is an organic compound with the formula C 6 H 5 C 6 H 4 NH 2.It is an amine derivative of biphenyl.It is a colorless solid, although aged samples can appear colored. 4-Aminobiphenyl was commonly used in the past as a rubber antioxidant and an intermediate for dyes. [5]
Certain azo dyes degrade under reductive conditions to release any of a group of defined aromatic amines. Since September 2003, the European Union has banned the manufacture or sale of consumer goods which contain the listed amines. Since only a small number of dyes produced those amines, relatively few products were actually affected. [4]
As with some other aromatic amines such as 2-naphthylamine, benzidine has been significantly withdrawn from use in most industries because it is so carcinogenic. In August 2010 benzidine dyes were included in the U.S. EPA's List of Chemicals of Concern. [ 7 ]
[3] 2-Aminophenol is an intermediate in the synthesis of dyes. It is particularly useful in yielding metal-complex dyes when diazotized and coupled to a phenol, naphthol, or other aromatic or resonant dye species. Metal complex dyes using copper or chromium are commonly used for producing dull colors.
Aniline (from Portuguese anil 'indigo shrub', and -ine indicating a derived substance) [6] is an organic compound with the formula C 6 H 5 NH 2.Consisting of a phenyl group (−C 6 H 5) attached to an amino group (−NH 2), aniline is the simplest aromatic amine.
With amines, one or more chloride is displaced. The remaining chlorides are reactive, and this theme is the basis of the large field of reactive dyes. Cyanuric chloride assists in the amidation of carboxylic acids. [3] The 1,2,4-triazines can react with electron-rich dienophiles in an inverse electron demand Diels-Alder reaction. This forms a ...