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Polyvinyl alcohol is used as an aid in suspension polymerizations. Its largest application in China is its use as a protective colloid to make PVAc dispersions. In Japan its major use is the production of Vinylon fiber. [7] This fiber is also manufactured in North Korea for self-sufficiency reasons, because no oil is required to produce it ...
Polyvinyl acetate used further for polyvinyl alcohol is manufactured by radical polymerization in methanol solution. Liquid polybutadienes are made by anionic or radical polymerization in hydrocarbon solutions. Butyl rubber (IIR) by low temperature cationic copolymerization of isobutylene with isoprene in ethylene or methylchloride solution.
One of the most common suspending agents is polyvinyl alcohol (PVA). [3] Usually, the monomer conversion is completed unlike in bulk polymerization , and the initiator used in this is monomer-soluble.
Many are produced using radical initiators which are produced from organic peroxides. Still others (polystyrene) are produced using anionic initiators such as butyl lithium. An exception from the usual rules, polyvinyl alcohol, (CH 2 CHOH) n, is produced by hydrolysis of polyvinyl acetate. Vinyl alcohol is not sufficiently stable to undergo ...
Vinyl alcohol, also called ethenol (IUPAC name; not ethanol) or ethylenol, is the simplest enol. With the formula C H 2 CH O H , it is a labile compound that converts to acetaldehyde immediately upon isolation near room temperature. [ 1 ]
Some grades of polyvinyl alcohol and other water-soluble polymers can promote emulsion polymerization even though they do not typically form micelles and do not act as surfactants (for example, they do not lower surface tension). It is believed that growing polymer chains graft onto these water-soluble polymers, which stabilize the resulting ...
Formvar refers to any of several thermoplastic resins that are polyvinyl formals, which are polymers formed from polyvinyl alcohol and formaldehyde as copolymers with polyvinyl acetate. They are typically used as coatings, adhesives, and molding materials. [1]
Ethylene vinyl alcohol (EVOH) is a formal copolymer of ethylene and vinyl alcohol. Because the latter monomer mainly exists as its tautomer acetaldehyde , the copolymer is prepared by polymerization of ethylene and vinyl acetate to give the ethylene vinyl acetate (EVA) copolymer followed by hydrolysis.
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