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The smaller number is always used, not the sum of the constituents numbers. The side chains are: an ethyl- at carbon 4, an ethyl- at carbon 8, and a butyl- at carbon 12. Note: the −O−CH 3 at carbon atom 15 is not a side chain, but it is a methoxy functional group. There are two ethyl- groups. They are combined to create, 4,8-diethyl.
The carbons of the chain are conventionally numbered from 1 to n, starting from the end which is closest to the carbonyl. If the carbonyl is at the very beginning of the chain (carbon 1), the monosaccharide is said to be an aldose, otherwise it is a ketose. These names can be combined with the chain length prefix, as in aldohexose or ...
To identify the preferred CRU, the chain is broken so that the senior ring is retained with the maximum number of heteroatoms and the minimum number of free valences. [12] An example is The preferred CRU is an acyclic subunit of 4 carbon atoms with 4 free valences, one at each atom, as shown.
Numbering of the carbon chain always begins at one bridgehead atom (where the rings meet) and follows the carbon chain along the longest path, to the next bridgehead atom. Then numbering is continued along the second longest path and so on. Fused and bridged bicyclic compounds get the prefix bicyclo, whereas spirocyclic compounds get the prefix ...
The main carbon chain is the longest possible continuous chain. The chemical affix denotes what type of molecule it is. For example, the ending ane denotes a single bonded carbon chain, as in "hexane" (C 6 H 14). [30] Another example of IUPAC organic nomenclature is cyclohexanol: Cyclohexanol. The substituent name for a ring compound is cyclo ...
The α-carbon is where the different substituents attach to each different amino acid. That is, the groups hanging off the chain at the α-carbon are what give amino acids their diversity. These groups give the α-carbon its stereogenic properties for every amino acid except for glycine.
The prefixes sec (from "secondary") and tert (from "tertiary") refer to the number of additional side chains (or carbons) connected to the first butyl carbon. The prefix "iso" or "iso" means "isolated" while the prefix 'n-' stands for "normal". Butan-2-yl (sec-butyl) group is chiral. The carbon atom at position 2 is a stereocenter.
The IUPAC's rules for naming organic and inorganic compounds are contained in two publications, known as the Blue Book [1] [2] and the Red Book, [3] respectively. A third publication, known as the Green Book , [ 4 ] recommends the use of symbols for physical quantities (in association with the IUPAP ), while a fourth, the Gold Book , [ 5 ...