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Lithium-based greases are the most commonly used; sodium and lithium-based greases have higher melting point (dropping point) than calcium-based greases but are not resistant to the action of water. Lithium-based grease has a dropping point at 190 to 220 °C (374 to 428 °F).
Lithium soap or greases, such as lithium stearate, are insoluble in water and find use in lubricating grease. Calcium and magnesium soaps are most commonly encountered as soap scum but the pure materials have a variety of uses. Magnesium stearate and calcium stearate are used as excipients, lubricants, release agents, and food additives, with ...
Lithium grease adheres particularly well to metal, is non-corrosive, may be used under heavy loads, and exhibits good temperature tolerance. It has a dropping point of 190 to 220 °C (370 to 430 °F) and resists moisture, so it is commonly used as lubricant in household products, such as electric garage doors, as well as in automotive ...
Lithium 12-hydroxystearate and other lithium-based fatty acids are important constituents of lubricating greases. In lithium-based greases, lithium carboxylates are thickeners. "Complex soaps" are also common, these being combinations of more than one acid salt, such as azelaic or acetic acid. [7]
So-called metallic soaps are key components of most lubricating greases and thickeners. [3] A commercially important example is lithium stearate. Greases are usually emulsions of calcium soap or lithium soap and mineral oil. Many other metallic soaps are also useful, including those of aluminium, sodium, and mixtures thereof.
They also form a constituent of the paste used to coat the lead-antimony-calcium or lead-antimony-selenium grids in a Lead-acid battery. Aqueous lignosulfonate solutions are also widely used as a non-toxic dust suppression agent for unpaved road surfaces, where it is popularly, if erroneously, called "tree sap".
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydrates. In the form of γ- anhydrite (the anhydrous form), it is used as a desiccant . One particular hydrate is better known as plaster of Paris , and another occurs naturally as the mineral gypsum .
Lithium 12-hydroxystearate exhibits high oxidation stability and a dropping point up to around 200 °C. Most greases used today in motor vehicles, aircraft, and heavy machinery contain lithium stearates, mainly lithium 12-hydroxystearate. [1] Greases can be made with the addition of several different metallic soaps.
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