Search results
Results from the WOW.Com Content Network
This lists the character tables for the more common molecular point groups used in the study of molecular symmetry. These tables are based on the group-theoretical treatment of the symmetry operations present in common molecules, and are useful in molecular spectroscopy and quantum chemistry. Information regarding the use of the tables, as well ...
The following table lists several notations for point groups: Hermann–Mauguin notation (used in crystallography), Schönflies notation (used to describe molecular symmetry), orbifold notation, and Coxeter notation. The latter three are not only conveniently related to its properties, but also to the order of the group.
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a concise form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions).
The first character tables were compiled by László Tisza (1933), in connection to vibrational spectra. Robert Mulliken was the first to publish character tables in English (1933), and E. Bright Wilson used them in 1934 to predict the symmetry of vibrational normal modes. [14]
The four-dimensional point groups (chiral as well as achiral) are listed in Conway and Smith, [1] Section 4, Tables 4.1–4.3. Finite isomorphism and correspondences. The following list gives the four-dimensional reflection groups (excluding those that leave a subspace fixed and that are therefore lower-dimensional reflection groups).
Point-group symbols in International Tables for Crystallography (2006). Vol. A, ch. 12.1, pp. 818-820; Names and symbols of the 32 crystal classes in International Tables for Crystallography (2006). Vol. A, ch. 10.1, p. 794; Pictorial overview of the 32 groups
In Hermann–Mauguin notation, space groups are named by a symbol combining the point group identifier with the uppercase letters describing the lattice type.Translations within the lattice in the form of screw axes and glide planes are also noted, giving a complete crystallographic space group.
Representative d-orbital splitting diagrams for square planar complexes featuring σ-donor (left) and σ+π-donor (right) ligands. A general d-orbital splitting diagram for square planar (D 4h) transition metal complexes can be derived from the general octahedral (O h) splitting diagram, in which the d z 2 and the d x 2 −y 2 orbitals are degenerate and higher in energy than the degenerate ...