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The thermal conductivity detector (TCD), also known as a katharometer, is a bulk property detector and a chemical specific detector commonly used in gas chromatography. [1] This detector senses changes in the thermal conductivity of the column eluent and compares it to a reference flow of carrier gas. Since most compounds have a thermal ...
The transient hot wire method has advantage over the other thermal conductivity methods, since there is a fully developed theory and there is no calibration or single-point calibration. Furthermore, because of the very small measuring time (1 s) there is no convection present in the measurements and only the thermal conductivity of the fluid is ...
Thermal radiation () End losses through the support structures; A heated metal wire (sensor wire, or simply sensor) suspended in a gas will lose heat to the gas as its molecules collide with the wire and remove heat. If the gas pressure is reduced, the number of molecules present will fall proportionately and the wire will lose heat more slowly.
A pellistor is a solid-state device [1] used to detect gases which are either combustible or which have a significant difference in thermal conductivity to that of air. The word "pellistor" is a combination of pellet and resistor.
The range of thermophysical properties can be covered by different forms of the technique, with the exception that the recommended thermal conductivity range where the highest precision can be attained is 0.01 to 150 W/m•K for the linear source freestanding sensor and 500 to 8000 J/m2•K•s0.5 for the planar source freestanding sensor.
Simplified schematic of a single gap chemiresistive sensor. (not to scale) A chemiresistor is a material that changes its electrical resistance in response to changes in the nearby chemical environment. [1] Chemiresistors are a class of chemical sensors that rely on the direct chemical interaction between the sensing material and the analyte. [2]
For example, a laboratory might conduct routinely acid/base, redox, complexometric, sulfate and chloride titrations. A single thermometric sensor in conjunction with an autosampler will enable all titrations to be performed in the same carousel load without having to change titration sensors.
Very high thermal conductivity measurements up to 22,600 w m −1 K −1 were reported by Fenton, E.W., Rogers, J.S. and Woods, S.D. in reference 570 on page 1458, 41, 2026–33, 1963. The data is listed on pages 6 through 8 and graphed on page 1 where Fenton and company are on curves 63 and 64.
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