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Capillary action of water (polar) compared to mercury (non-polar), in each case with respect to a polar surface such as glass (≡Si–OH). Capillary action (sometimes called capillarity, capillary motion, capillary rise, capillary effect, or wicking) is the process of a liquid flowing in a narrow space without the assistance of external forces like gravity.
Cohesion, along with adhesion (attraction between unlike molecules), helps explain phenomena such as meniscus, surface tension and capillary action. Mercury in a glass flask is a good example of the effects of the ratio between cohesive and adhesive forces.
The effect is observed in small objects which are supported by the surface of a liquid. There are two types of such objects: objects which are sufficiently buoyant that they will always float on the surface (for example, Cheerios in milk), and objects which are heavy enough to sink when immersed, but not so heavy as to overcome the surface tension of the liquid (for example, steel pins on water).
When a tube of a narrow bore, often called a capillary tube, is dipped into a liquid and the liquid wets the tube (with zero contact angle), the liquid surface inside the tube forms a concave meniscus, which is a virtually spherical surface having the same radius, r, as the inside of the tube. The tube experiences a downward force of magnitude ...
Capillary pressure can also be utilized to block fluid flow in a microfluidic device. A schematic of fluid flowing through a microfluidic device by capillary action (refer to image of capillary rise of water for left and right contact angles in microfluidic channels) The capillary pressure in a microchannel can be described as:
Water potential is the potential energy of water per unit volume relative to pure water in reference conditions. Water potential quantifies the tendency of water to move from one area to another due to osmosis, gravity, mechanical pressure and matrix effects such as capillary action (which is caused by surface tension).
According to Nikolaides, the electrostatic force engenders a long range capillary attraction. However, this explanation is controversial; other authors have argued that the capillary effect of the electrodipping force is in fact cancelled by the electrostatic pressure on the interface, so the resulting capillary effect would be insignificant.
Capillary bridges also may form between two liquids. [1] Plateau defined a sequence of capillary shapes [2] known as (1) nodoid with 'neck', (2) catenoid, (3) unduloid with 'neck', (4) cylinder, (5) unduloid with 'haunch' (6) sphere and (7) nodoid with 'haunch'. The presence of capillary bridge, depending on their shapes, can lead to attraction ...