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For elements that have multiple allotropes, the reference state usually is chosen to be the form in which the element is most stable under 1 bar of pressure. One exception is phosphorus, for which the most stable form at 1 bar is black phosphorus, but white phosphorus is chosen as the standard reference state for zero enthalpy of formation. [2]
The ΔH° form undergoes discontinuities at a phase transition temperatures of the constituent element(s) and the compound. The enthalpy change for any standard reaction is designated ΔH° rx. Standard molar heat of formation of ZnBr 2 (c,l) from the elements, showing discontinuities at transition temperatures of the elements and the compound.
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J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Element Origin of name [1] [2] Group Period Block Standard atomic weight A r °(E) [a] Density [b] [c] Melting point [d] Boiling point [e] Specific heat capacity [f] Electronegativity [g] Abundance in Earth's crust [h] Origin [i] Phase at r.t. [j] Atomic number Z Symbol Name ( g / cm 3 ) (K) ( J / g · K ) ( mg / kg ) 1 H ...
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