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The inductive effect is the transmission of charge through covalent bonds and Bent's rule provides a mechanism for such results via differences in hybridisation. In the table below, [ 26 ] as the groups bonded to the central carbon become more electronegative, the central carbon becomes more electron-withdrawing as measured by the polar ...
The Williamson ether synthesis is an organic reaction, forming an ether from an organohalide and a deprotonated alcohol (alkoxide). This reaction was developed by Alexander Williamson in 1850. [2] Typically it involves the reaction of an alkoxide ion with a primary alkyl halide via an S N 2 reaction. This reaction is important in the history of ...
Ether. The general structure of an ether. R and R' represent most organyl substituents. In organic chemistry, ethers are a class of compounds that contain an ether group —an oxygen atom bonded to two organyl groups (e.g., alkyl or aryl). They have the general formula R−O−R′, where R and R′ represent the organyl groups.
In chemistry, a non-covalent interaction differs from a covalent bond in that it does not involve the sharing of electrons, [1] but rather involves more dispersed variations of electromagnetic interactions between molecules or within a molecule. The chemical energy released in the formation of non-covalent interactions is typically on the order ...
C-symmetry. In physics, charge conjugation is a transformation that switches all particles with their corresponding antiparticles, thus changing the sign of all charges: not only electric charge but also the charges relevant to other forces. The term C-symmetry is an abbreviation of the phrase "charge conjugation symmetry", and is used in ...
Charge transfer coefficient. Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions. The symmetry factor and the charge transfer coefficient are ...
Bonds made and broken are labelled blue and red, respectively. The inverse electron demand Diels–Alder reaction, or DAINV or IEDDA[1] is an organic chemical reaction, in which two new chemical bonds and a six-membered ring are formed. It is related to the Diels–Alder reaction, but unlike the Diels–Alder (or DA) reaction, the DA INV is a ...
The bond angle for water is 104.5°. Valence shell electron pair repulsion (VSEPR) theory (/ ˈvɛspər, vəˈsɛpər / VESP-ər, [1]: 410 və-SEP-ər[2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3] It is also named the Gillespie-Nyholm ...