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The compound (C 5 H 5) 2 TiS 5 is an example of a polysulfide complex. Polysulfides are a class of chemical compounds derived from anionic chains of sulfur atoms. [1] There are two main classes of polysulfides: inorganic and organic. The inorganic polysulfides have the general formula S 2− n. These anions are the conjugate bases of ...
In 1838, Swiss chemists reported the preparation of hydrophobic rubbery materials by the alkylation of sodium polysulfide with 1,2-dichloroethane. [2] In 1926 chemists Joseph C. Patrick and Nathan Mnookin further developed this class of materials, which first achieved commercial success as sealants for fuel lines, exploiting the solvent resistance of these materials.
kg/kg 1: intensive (Mass) Density (or volume density) ρ: Mass per unit volume kg/m 3: L −3 M: intensive Mean lifetime: τ: Average time for a particle of a substance to decay s T: intensive Molar concentration: C: Amount of substance per unit volume mol⋅m −3: L −3 N: intensive Molar energy: J/mol: Amount of energy present in a system ...
Sodium polysulfide is a general term for salts with the formula Na 2 S x, where x = 2 to 5. The species S x 2−, called polysulfide anions, include disulfide (S 2 2−), trisulfide (S 3 2−), tetrasulfide (S 4 2−), and pentasulfide (S 5 2−).
Na 2 S 4 + 2 ClC 3 H 6 Si(OEt) 3 → S 4 [C 3 H 6 Si(OEt) 3] 2 + 2 NaCl Bis(triethoxysilylpropyl)tetrasulfide is a bifunctional molecule in that it contains two kinds of reactive functional groups . The tetrasulfide group is a polysulfide , which means that it consists of a chain of sulfur atoms.
Sealant is a substance used to block the passage of fluids through openings in materials, [1] a type of mechanical seal. In building construction sealant is sometimes synonymous with caulk (especially if acrylic latex or polyurethane based) [ 2 ] and also serve the purposes of blocking dust, sound and heat transmission.
Specific surface area (SSA) is a property of solids defined as the total surface area (SA) of a material per unit mass, [1] (with units of m 2 /kg or m 2 /g). Alternatively, it may be defined as SA per solid or bulk volume [ 2 ] [ 3 ] (units of m 2 /m 3 or m −1 ).
CH 3 C 6 H 4 SO 2 Cl + R 2 NH → CH 3 C 6 H 4 SO 2 NR 2 + HCl. The resulting sulfonamides are non-basic and, when derived from primary amines, are even acidic. TsCl reacts with hydrazine to give p-toluenesulfonyl hydrazide. The preparation of tosyl esters and amides are conducted in the presence of a base, which absorbs hydrogen chloride.