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2,6-Dimethylnaphthalene is mainly used for the preparation of 2,6-naphthalenedicarboxylic acid by oxidation of 2,6-dimethylnaphthalene in the liquid phase. 2,6-Naphthalenedicarboxylic acid is a monomer for the production of high-performance polymers, in particular poly (ethylene-2,6-naphthalene dicarboxylate) or shorter polyethylene naphthalate (PEN). [4]
It was first prepared by Robert Evert and Victor Merz in 1876 by hydrolysis of 2,6-dicyanonaphthalene. [2] [3] 1,8-Naphthalenedicarboxylic acid can be isomerized to 2,6-naphthalenedicarboxylic acid via the intermediacy of the dipotassium dicarboxylates. [2] It is also produced by oxidation of 2,6-diisopropylnaphthalene. [4]
Synthesis of symmetric and unsymmetric NDIs. NTCDI is redox-active, forming stable radical anions at –1.10 V vs. Fc/Fc + in Dichloromethane. [5] Its ability to accept electrons reflects the presence of an extended conjugated ring system and the electron withdrawing groups (carbonyl centers).
The last two isomers of DMMDA are 5,6-dimethoxy-2,3-methylenedioxy-1-α-methylphenylethylamine and 4,6-dimethoxy-2,3-methylenedioxy-1-α-methylphenylethylamine. Like all other α-methylphenylethylamine derivative compounds, DMMDA and its regioisomer have two enantiomers due to the methyl group being in the alpha position of the ethyl group in ...
Naphthalenetetracarboxylic dianhydride (NTDA) is an organic compound related to naphthalene. The compound is a beige solid. The compound is a beige solid. NTDA is most commonly used as a precursor to naphthalenediimides (NDIs) (such as napthalenetetracarboxylic diimide ), a family of compounds with many uses.
Dimethoxyethane, also known as glyme, monoglyme, dimethyl glycol, ethylene glycol dimethyl ether, dimethyl cellosolve, and DME, is a colorless, aprotic, and liquid ether that is used as a solvent, especially in batteries. [2]
Diaminonaphthalene describes several isomers containing naphthalene substituted with two amine groups (NH 2), also called naphthalenediamines. All isomers are white solids that tend to air-oxidize. The 2,3-, 1,5-, and 1,8- derivatives have attracted most attention. 1,2-Diaminonaphthalene 938-25-0 [1] 1,3-Diaminonaphthalene 24824-28-0 [2]
A solution of lithium naphthalenide, the lithium salt of naphthalene, in tetrahydrofuran. The alkali metal naphthalene salts are prepared by stirring the metal with naphthalene in an ethereal solvent, usually as tetrahydrofuran or dimethoxyethane. The resulting salt is dark green. [2] [3] [4] The anion is a radical, giving a strong EPR signal ...