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The first constitutive equation (constitutive law) was developed by Robert Hooke and is known as Hooke's law.It deals with the case of linear elastic materials.Following this discovery, this type of equation, often called a "stress-strain relation" in this example, but also called a "constitutive assumption" or an "equation of state" was commonly used.
This constitutive equation is also called the Newton law of viscosity. The total stress tensor σ {\displaystyle {\boldsymbol {\sigma }}} can always be decomposed as the sum of the isotropic stress tensor and the deviatoric stress tensor ( σ ′ {\displaystyle {\boldsymbol {\sigma }}'} ):
The constitutive relation is expressed as a linear first-order differential equation: = + ˙ This model represents a solid undergoing reversible, viscoelastic strain. Upon application of a constant stress, the material deforms at a decreasing rate, asymptotically approaching the steady-state strain.
The conservation laws, which in the context of transport phenomena are formulated as continuity equations, describe how the quantity being studied must be conserved. The constitutive equations describe how the quantity in question responds to various stimuli via transport
In chemistry, dimerization is the process of joining two identical or similar molecular entities by bonds. The resulting bonds can be either strong or weak. Many symmetrical chemical species are described as dimers, even when the monomer is unknown or highly unstable. [1] The term homodimer is used when the two subunits are identical (e.g.
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
The most fundamental concept in chemistry is the law of conservation of mass, which states that there is no detectable change in the quantity of matter during an ordinary chemical reaction. Modern physics shows that it is actually energy that is conserved, and that energy and mass are related; a concept which becomes important in nuclear chemistry.
The concept is the same as for a large mass balance, but it is performed in the context of a limiting system (for example, one can consider the limiting case in time or, more commonly, volume). A differential mass balance is used to generate differential equations that can provide an effective tool for modelling and understanding the target system.