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1-Chloronaphthalene is obtained directly by chlorination of naphthalene, with the formation of more highly substituted derivatives such as dichloro- and trichloronaphthalenes in addition to the two monochlorinated isomeric compounds: 1-chloronaphthalene and 2-chloronaphthalene. [2]
For example, chlorination and bromination of naphthalene proceeds without a catalyst to give 1-chloronaphthalene and 1-bromonaphthalene, respectively. Likewise, whereas both benzene and naphthalene can be alkylated using Friedel–Crafts reaction conditions, naphthalene can also be easily alkylated by reaction with alkenes or alcohols , using ...
Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes as a solvate with ligands bound to Na +. [1]
1-Naphthol, or α-naphthol, is an organic compound with the formula C 10 H 7 OH. It is a fluorescent white solid. 1-Naphthol differs from its isomer 2-naphthol by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol. Both isomers are soluble in simple organic solvents. They are ...
Chloral is produced commercially by the chlorination of acetaldehyde in the presence of hydrochloric acid, producing chloral hydrate. Ethanol can also be used as a feedstock. This reaction is catalyzed by antimony trichloride: H 3 CCHO + 3 Cl 2 + H 2 O → Cl 3 CCH(OH) 2 + 3 HCl. The chloral hydrate is distilled from the reaction mixture.
Polychlorinated naphthalene (PCN) are the products obtained upon treatment of naphthalene with chlorine. The generic chemical formula is C 10 H 8−(m+n) Cl (m+n) . Commercial PCNs are mixtures of up to 75 components and byproducts. [ 1 ]
Thus, for example, "15 mg/L of available chlorine" means that the amount of product contained in one liter of the liquid has the same oxidizing power as 15 mg of chlorine. [ 24 ] [ 25 ] The strength of commercial chlorine-releasing products may be instead specified as the concentration of the active ingredient, as mass or weight percent or ...
A practical synthesis involves the tin/HCl-reduction of the naphthalene-1-sulfonyl chloride. [1] 1-Naphthalenethiol can also be prepared from 1-bromonaphthalene by Pd-catalyzed reaction with the silylthiolate i Pr 3 SiSK followed by hydrolysis of the silathioether. [2] It was first prepared from the Grignard reagent generated from 1 ...