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In order for galvanic cathodic protection to work, the anode must possess a lower (that is, more negative) electrode potential than that of the cathode (the target structure to be protected). The table below shows a simplified galvanic series which is used to select the anode metal. [13]
In brief, corrosion is a chemical reaction occurring by an electrochemical mechanism (a redox reaction). [1] During corrosion of iron or steel there are two reactions, oxidation (equation 1), where electrons leave the metal (and the metal dissolves, i.e. actual loss of metal results) and reduction, where the electrons are used to convert oxygen and water to hydroxide ions (equation 2): [2]
The terms anode and cathode are not defined by the voltage polarity of electrodes, but are usually defined by the direction of current through the electrode. An anode usually is the electrode of a device through which conventional current (positive charge) flows into the device from an external circuit, while a cathode usually is the electrode through which conventional current flows out of ...
Simple scheme of the apparatus for electro-oxidation process. The set-up for performing an electro-oxidation treatment consists of an electrochemical cell.An external electric potential difference (aka voltage) is applied to the electrodes, resulting in the formation of reactive species, namely hydroxyl radicals, in the proximity of the electrode surface. [11]
If DC voltage is used, electrolysis of water occurs, decomposing water into its elements H 2 at the cathode (negative electrode) and O 2 at the anode (positive electrode). The electrode boiler is 99.9% efficient with almost all the energy consumed producing steam. [1] Losses are radiant heat from the vessel only.
In cathodic protection, the anode groundbed is the arrangement of anodes in the ground or water and it provides the path for protective current to leave the anodes and enter to electrolyte. [ 6 ] High voltage direct current systems
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