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In electrical engineering, impedance is the opposition to alternating current presented by the combined effect of resistance and reactance in a circuit. [1]Quantitatively, the impedance of a two-terminal circuit element is the ratio of the complex representation of the sinusoidal voltage between its terminals, to the complex representation of the current flowing through it. [2]
In electrochemistry, faradaic impedance [1] [2] is the resistance and capacitance acting jointly at the surface of an electrode of an electrochemical cell. The cell may be operating as either a galvanic cell generating an electric current or inversely as an electrolytic cell using an electric current to drive a chemical reaction .
Randles circuit schematic. In electrochemistry, a Randles circuit is an equivalent electrical circuit that consists of an active electrolyte resistance R S in series with the parallel combination of the double-layer capacitance C dl and an impedance (Z w) of a faradaic reaction.
The converse also holds: if a current source in parallel with an impedance is present, multiplying the value of the current source with the value of the impedance provides the equivalent voltage source in series with the impedance. A visual example of a source transformation can be seen in Figure 1.
Practical impedance-matching devices will generally provide best results over a specified frequency band. The concept of impedance matching is widespread in electrical engineering, but is relevant in other applications in which a form of energy, not necessarily electrical, is transferred between a source and a load, such as in acoustics or optics.
A common example of an "active resistance" circuit is the negative impedance converter (NIC) [45] [46] [115] [125] shown in the diagram. The two resistors R 1 {\displaystyle R_{\text{1}}} and the op amp constitute a negative feedback non-inverting amplifier with gain of 2. [ 115 ]
This technique measures the impedance of a system over a range of frequencies, and therefore the frequency response of the system, including the energy storage and dissipation properties, is revealed. Often, data obtained by electrochemical impedance spectroscopy (EIS) is expressed graphically in a Bode plot or a Nyquist plot.
Equivalent unbalanced and balanced networks. The impedance of the series elements in the balanced version is half the corresponding impedance of the unbalanced version. Fig. 3. To be balanced, a network must have the same impedance in each "leg" of the circuit. A 3-terminal network can also be used as a 2-port.