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Class 3: Flammable Liquids A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions ...
Includes flammable liquids with flash points below 73 °F (23 °C) and boiling points above 100 °F (38 °C), as well as liquids with flash points between 73 °F and 100 °F. 2. Materials which must be moderately heated or exposed to high ambient temperatures before ignition will occur.
Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 37.8 °C/100 °F. Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids.
Substances and mixtures which, in contact with water, emit flammable gases are categorized from 1 to 3 based on the ignitability of the gas emitted. Oxidizing liquids contribute to the combustion of other materials and are categorized from 1 to 3 in decreasing oxidizing potential. Oxidizing solids follow the same criteria as oxidizing liquids.
Flammable gases – Gases which at 20 °C and a standard pressure of 101.3 kPa: are ignitable when in a mixture of 13 percent or less by volume with air; or; have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Alternative sign. Division 2.1 Non-flammable non-toxic gases – Gases which:
n.o.s. = not otherwise specified meaning a collective entry to which substances, mixtures, solutions or articles may be assigned if a) they are not mentioned by name in 3.2 Dangerous Goods List AND b) they exhibit chemical, physical and/or dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.o.s. entry [4]
UN Number Class Proper Shipping Name UN 2901: 2.3: Bromine chloride: UN 2902: 6.1: Pesticides, liquid, toxic, n.o.s. : UN 2903: 6.1: Pesticides, liquid, toxic ...
Paint, corrosive, flammable or Paint related material, corrosive, flammable UN 3471: 8: Hydrogen difluorides solution, n.o.s. UN 3472: 8: Crotonic acid, liquid UN 3473: 3: Fuel cell cartridges, or Fuel cell cartridges contained in equipment or Fuel cell cartridges packed with equipment, containing flammable liquids UN 3474: 4.1
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