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Zinc plating was developed, and continues to evolve, to meet the most challenging corrosion protection, temperature, and wear resistance requirements. Electroplating of zinc was invented in 1800 but the first bright deposits were not obtained until the early 1930s with the alkaline cyanide electrolyte.
Many plating baths include cyanides of other metals (such as potassium cyanide) in addition to cyanides of the metal to be deposited. These free cyanides facilitate anode corrosion, help to maintain a constant metal ion level, and contribute to conductivity.
The process is similar to that of Electrolytic sulfuric acid zinc plating, with few differences from bethanization. The electrolytic sulfuric acid zinc plating process uses zinc anodes, while bethanization uses inert mild steel anodes instead. The electrolytes used are manufactured by using zinc oxide dross, and dissolving it in sulfuric acid. [2]
Immersion zinc plating is an electroless (non-electrolytic) coating process that deposits a thin layer of zinc on a less electronegative metal, by immersion in a solution containing a zinc or zincate ions, Zn(OH) 2− 4. A typical use is plating aluminum with zinc prior to electrolytic or electroless nickel plating.
Galvanizing with zinc protects the steel base metal by sacrificial anodic action. Cathodic protection uses one or more sacrificial anodes made of a metal which is more active than the protected metal. Alloys of metals commonly used for sacrificial anodes include zinc, magnesium, and aluminium. This approach is commonplace in water heaters and ...
Zinc is considered a reliable material, but is not suitable for use at higher temperatures, as it tends to passivate (the oxide layer formed shields from further oxidation); if this happens, current may cease to flow and the anode stops working. [10] Zinc has a relatively low driving voltage, which means in higher-resistivity soils or water it ...
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