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Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
Here, is the overall mass transfer coefficient, which could be determined by empirical correlations, is the surface area for mass transfer (particularly relevant in membrane-based separations), and ˙ is the mass flowrate of bulk fluid (e.g., mass flowrate of air in an application where water vapor is being separated from the air mixture). At ...
The heat transfer coefficient has SI units in watts per square meter per kelvin (W/(m 2 K)). The overall heat transfer rate for combined modes is usually expressed in terms of an overall conductance or heat transfer coefficient, U. In that case, the heat transfer rate is: ˙ = where (in SI units):
This rate can be quantified through the calculation and application of mass transfer coefficients for an overall process. These mass transfer coefficients are typically published in terms of dimensionless numbers, often including Péclet numbers, Reynolds numbers, Sherwood numbers, and Schmidt numbers, among others. [2] [3] [4]
This equation permits the prediction of an unknown transfer coefficient when one of the other coefficients is known. The analogy is valid for fully developed turbulent flow in conduits with Re > 10000, 0.7 < Pr < 160, and tubes where L/d > 60 (the same constraints as the Sieder–Tate correlation). The wider range of data can be correlated by ...
For best accuracy, n should be adjusted where correlations have a different exponent. We can take this further by substituting into this equation the definitions of the heat transfer coefficient, mass transfer coefficient, and Lewis number, yielding: = =
The Sherwood number (Sh) (also called the mass transfer Nusselt number) is a dimensionless number used in mass-transfer operation. It represents the ratio of the total mass transfer rate ( convection + diffusion) to the rate of diffusive mass transport, [ 1 ] and is named in honor of Thomas Kilgore Sherwood .
The equations for the use of the data retrieved from these tables are very simple. Q= heat gain, usually heat gain per unit time A= surface area. U= Overall heat transfer coefficient. CLTD= cooling load temperature difference SCL= solar cooling load factor CLF= cooling load factor SC= shading coefficient