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  2. Rate equation - Wikipedia

    en.wikipedia.org/wiki/Rate_equation

    In organic chemistry, the class of S N 1 (nucleophilic substitution unimolecular) reactions consists of first-order reactions. For example, in the reaction of aryldiazonium ions with nucleophiles in aqueous solution, ArN + 2 + X − → ArX + N 2, the rate equation is = [+], where Ar indicates an aryl group. [23]

  3. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :

  4. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    As an example, consider the gas-phase reaction NO 2 + CO → NO + CO 2.If this reaction occurred in a single step, its reaction rate (r) would be proportional to the rate of collisions between NO 2 and CO molecules: r = k[NO 2][CO], where k is the reaction rate constant, and square brackets indicate a molar concentration.

  5. Single displacement reaction - Wikipedia

    en.wikipedia.org/wiki/Single_displacement_reaction

    A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [1] [2] [3] It can be represented generically as: + +

  6. Chemical reaction - Wikipedia

    en.wikipedia.org/wiki/Chemical_reaction

    For example, when barium chloride (BaCl 2) and magnesium sulfate (MgSO 4) react, the SO 4 2− anion switches places with the 2Cl − anion, giving the compounds BaSO 4 and MgCl 2. Another example of a double displacement reaction is the reaction of lead(II) nitrate with potassium iodide to form lead(II) iodide and potassium nitrate : Pb ( NO 3 ...

  7. Cross-coupling reaction - Wikipedia

    en.wikipedia.org/wiki/Cross-coupling_reaction

    In organic chemistry, a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the more general coupling reactions. Cross-couplings are a subset of the more general coupling reactions.

  8. Rearrangement reaction - Wikipedia

    en.wikipedia.org/wiki/Rearrangement_reaction

    In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...

  9. Group transfer reaction - Wikipedia

    en.wikipedia.org/wiki/Group_transfer_reaction

    In organic chemistry, a group transfer reaction is a class of the pericyclic reaction where one or more groups of atoms is transferred from one molecule to another. Group transfer reactions can sometimes be difficult to identify when separate reactant molecules combine into a single product molecule (like in the ene reaction).

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