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Methanol (CH 3 OH) is less expensive to sustainably produce than ethanol fuel, although it is more toxic than ethanol and has a lower energy density than gasoline. Methanol is safer for the environment than gasoline, is an anti-freeze agent, prevents dirt and grime buildup within the engine, has a higher ignition temperature and can withstand ...
Ethanol is an attractive alternative to methanol because it comes with a supply chain that's already in place. Ethanol also remains the easier fuel to work with for widespread use by consumers. Ethanol is a hydrogen-rich liquid and it has a high energy density (8.0 kWh/kg) compared to methanol (6.1 kWh/kg
Methanol and ethanol are incompatible with some polymers. The alcohol reacts with the polymers causing swelling, and over time oxygen breaks down the carbon-carbon bonds in the polymer causing a reduction in tensile strength. For the past few decades though, most cars have been designed to tolerate up to 10% ethanol (E10) without problem.
The fraction of water that an ethanol-gasoline fuel can contain without phase separation increases with the percentage of ethanol. [29] For example, E30 can have up to about 2% water. If there is more than about 71% ethanol, the remainder can be any proportion of water or gasoline and phase separation does not occur.
Ethanol has close to 34% less energy per volume than gasoline, [53] [54] consequently fuel economy ratings with ethanol blends are significantly lower than with pure gasoline, but this lower energy content does not translate directly into a 34% reduction in mileage, because there are many other variables that affect the performance of a ...
Methanol is a promising energy carrier because, as a liquid, it is easier to store than hydrogen and natural gas. Its energy density is, however, lower than methane , per kg. Its combustion energy density is 15.6 MJ / L ( LHV ), whereas that of ethanol is 24 and gasoline is 33 MJ/L.
This is known as oxygenated fuel and often (but not entirely correctly, as there are reformulated gasolines without oxygenate) as reformulated gasoline. Methyl tert-butyl ether (MTBE) was the most common fuel additive in the United States, prior to government mandated use of ethanol. Typically, gasoline with added MTBE is called reformulated ...
By convention, the (higher) heat of combustion is defined to be the heat released for the complete combustion of a compound in its standard state to form stable products in their standard states: hydrogen is converted to water (in its liquid state), carbon is converted to carbon dioxide gas, and nitrogen is converted to nitrogen gas.