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2,4,5-Trichlorophenoxyacetic acid (also known as 2,4,5-T), a synthetic auxin, is a chlorophenoxy acetic acid herbicide used to defoliate broad-leafed plants. It was developed in the late 1940s, synthesized by reaction of 2,4,5-Trichlorophenol and chloroacetic acid. It was widely used in the agricultural industry until being phased out, starting ...
One major complication to the use of herbicides for weed control is the ability of plants to evolve herbicide resistance, rendering the herbicides ineffective against target plants. Out of 31 known herbicide modes of action, weeds have evolved resistance to 21. 268 plant species are known to have evolved herbicide resistance at least once. [59]
The use of DCPA as a herbicide was first described in a patent filed in 1958. [12] The material was prepared as had been described in a 1948 research paper by treating terephthaloyl chloride with chlorine to give tetrachloroterephthaloyl chloride which was then esterified with methanol. [13] C 6 H 4 (COCl) 2 + 4 Cl 2 + Fe (cat.) → C 6 Cl 4 ...
It was recognized as toxic and was combined with large amounts of water or oil to function as a weed-killer. Army experiments with the chemical eventually led to the discovery that 2,4-D combined with 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) yielded a more potent herbicide. [1]
In the United States as of 2014, atrazine was the second-most widely used herbicide after glyphosate, [16] with 76 million pounds (34 thousand metric tons) of it applied each year, [19] [20] nearly identical to its usage in 1974, of 76.8 million pounds. [21] Atrazine continues to be one of the most widely used herbicides in Australian ...
2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) 2,4-dichlorophenoxyacetic acid (2,4-D) 2,4,5-trichlorophenoxyacetic acid (2,4,5-T). The active ingredient of Agent Orange was an equal mixture of two phenoxy herbicides – 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) – in iso-octyl ester form, which contained traces of the dioxin 2,3,7,8-tetrachlorodibenzo ...
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