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Gas properties Std enthalpy change ... Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. Ethane vapor pressure vs. temperature.
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
Although ethane is a greenhouse gas, it is much less abundant than methane, has a lifetime of only a few months compared to over a decade, [30] and is also less efficient at absorbing radiation relative to mass. In fact, ethane's global warming potential largely results from its conversion in the atmosphere to methane. [31]
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
Bond lengths are measured in the solid phase by means of X-ray diffraction, or approximated in the gas phase by microwave spectroscopy. A bond between a given pair of atoms may vary between different molecules. For example, the carbon to hydrogen bonds in methane are different from those in methyl chloride. It is however possible to make ...
The bond energy for H 2 O is the average energy required to break each of the two O–H bonds in sequence: Although the two bonds are the equivalent in the original symmetric molecule, the bond-dissociation energy of an oxygen–hydrogen bond varies slightly depending on whether or not there is another hydrogen atom bonded to the oxygen atom.
For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated. Alternatively, the compressibility factor for specific gases can be read from generalized compressibility charts [ 1 ] that plot Z {\displaystyle Z} as a function of pressure at ...
The term bond-dissociation energy is similar to the related notion of bond-dissociation enthalpy (or bond enthalpy), which is sometimes used interchangeably.However, some authors make the distinction that the bond-dissociation energy (D 0) refers to the enthalpy change at 0 K, while the term bond-dissociation enthalpy is used for the enthalpy change at 298 K (unambiguously denoted DH° 298).