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  2. Van der Waals constants (data page) - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_constants...

    Benzene: 18.24 0.1193 Bromobenzene: 28.94 0.1539 Butane: 14.66 0.1226 1-Butanol [2] 20.94 0.1326 2-Butanone [2] 19.97 0.1326 Carbon dioxide: 3.640 0.04267 Carbon disulfide: 11.77 0.07685 Carbon monoxide: 1.505 0.0398500 Carbon tetrachloride: 19.7483 0.1281 Chlorine: 6.579 0.05622 Chlorobenzene: 25.77 0.1453 Chloroethane: 11.05 0.08651 ...

  3. Alcohol oxidation - Wikipedia

    en.wikipedia.org/wiki/Alcohol_oxidation

    Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.

  4. Wacker process - Wikipedia

    en.wikipedia.org/wiki/Wacker_process

    This net reaction can also be described as follows: [PdCl 4] 2 − + C 2 H 4 + H 2 O → CH 3 CHO + Pd + 2 HCl + 2 Cl −. This conversion is followed by reactions that regenerate the Pd(II) catalyst: Pd + 2 CuCl 2 + 2 Cl − → [PdCl 4] 2− + 2 CuCl 2 CuCl + ⁠ 1 / 2 ⁠ O 2 + 2 HCl → 2 CuCl 2 + H 2 O. Only the alkene and oxygen are consumed.

  5. Ethane - Wikipedia

    en.wikipedia.org/wiki/Ethane

    The combustion of ethane releases 1559.7 kJ/mol, or 51.9 kJ/g, of heat, and produces carbon dioxide and water according to the chemical equation: 2 C 2 H 6 + 7 O 2 → 4 CO 2 + 6 H 2 O + 3120 kJ. Combustion may also occur without an excess of oxygen, yielding carbon monoxide, acetaldehyde, methane, methanol, and ethanol.

  6. Alcohol (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Alcohol_(chemistry)

    The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...

  7. Carbonyl reduction - Wikipedia

    en.wikipedia.org/wiki/Carbonyl_reduction

    In organic chemistry, carbonyl reduction is the conversion of any carbonyl group, usually to an alcohol. It is a common transformation that is practiced in many ways. [ 1 ] Ketones , aldehydes , carboxylic acids , esters , amides , and acid halides - some of the most pervasive functional groups , -comprise carbonyl compounds.

  8. Bond-dissociation energy - Wikipedia

    en.wikipedia.org/wiki/Bond-dissociation_energy

    The term bond-dissociation energy is similar to the related notion of bond-dissociation enthalpy (or bond enthalpy), which is sometimes used interchangeably.However, some authors make the distinction that the bond-dissociation energy (D 0) refers to the enthalpy change at 0 K, while the term bond-dissociation enthalpy is used for the enthalpy change at 298 K (unambiguously denoted DH° 298).

  9. Methoxy group - Wikipedia

    en.wikipedia.org/wiki/Methoxy_group

    In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen. This alkoxy group has the formula R−O−CH 3. On a benzene ring, the Hammett equation classifies a methoxy substituent at the para position as an electron-donating group, but as an electron-withdrawing group if at the meta position.