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In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula −OH and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry , alcohols and carboxylic acids contain one or more hydroxy groups.
Structure of the hydroxyl (-OH) functional group. The suffix –ol is used in organic chemistry principally to form names of organic compounds containing the hydroxyl (–OH) group, mainly alcohols. The suffix was extracted from the word alcohol. The suffix also appears in some trivial names with reference to oils (from Latin oleum, oil).
Meaning SI unit of measure alpha: alpha particle: angular acceleration: radian per second squared (rad/s 2) fine-structure constant: unitless beta: velocity in terms of the speed of light c: unitless beta particle: gamma: Lorentz factor: unitless photon: gamma ray: shear strain: radian
Ultimately, both reactions generate hydroxyl radicals. These radicals are oxidative in nature and nonselective with a redox potential of E 0 = +3.06 V. [24] This is significantly greater than many common organic compounds, which typically are not greater than E 0 = +2.00 V. [25] This results in the non-selective oxidative behavior of these ...
The hydroxyl radical, Lewis structure shown, contains one unpaired electron. Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron.
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
For example, in the cyclic alcohol inositol (a six-fold alcohol of cyclohexane), the six-carbon cyclic backbone largely prevents the hydroxyl and the hydrogen on each carbon from switching places. Therefore, one has different configurational isomers depending on whether each hydroxyl is on "this side" or "the other side" of the ring's mean plane.
Hydroxyl groups (-OH), found in alcohols, are polar and therefore hydrophilic (water liking) but their carbon chain portion is non-polar which make them hydrophobic. The molecule increasingly becomes overall more nonpolar and therefore less soluble in the polar water as the carbon chain becomes longer. [ 5 ]