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A violet color indicates still alkaline areas and thus non-carbonated concrete. Carbonated zones favorable for steel corrosion and concrete degradation are colorless. [3] [4] The presence of water in carbonated concrete is necessary to lower the pH of concrete pore water around rebar and to depassivate the carbon steel surface at low pH.
A fairly well-defined reaction front can often be observed in thin sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and the microstructure of concrete are modified. These changes may vary in type or severity but commonly include: Extensive cracking; Expansion
NACE International Standard TM0208 defines volatile corrosion inhibitor (VCI) as a chemical substance that acts to reduce corrosion by a combination of volatilization from a VCI material, vapor transport in the atmosphere of an enclosed environment, and condensation onto surface in the space, including absorption, dissolution, and hydrophobic ...
The effectiveness of a corrosion inhibitor depends on fluid composition and dynamics. Corrosion inhibitors are common in industry, and also found in over-the-counter products, typically in spray form in combination with a lubricant and sometimes a penetrating oil. They may be added to water to prevent leaching of lead or copper from pipes. [2]
Carbonatation induced rebar corrosion. Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...
In sewerage areas where biogenic sulfide corrosion is expected, acid-resistant materials like calcium aluminate cements, PVC or vitrified clay pipe may be substituted to ordinary concrete or steel sewers. Existing structures that have extensive exposure to biogenic corrosion such as sewer manholes and pump station wet wells can be rehabilitated.
Concrete sealers are applied to concrete to protect it from surface damage, corrosion, and staining. They either block the pores in the concrete to reduce absorption of water and salts or form an impermeable layer which prevents such materials from passing.
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