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The hydroxyl radical, Lewis structure shown, contains one unpaired electron. Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron.
Radical disproportionation encompasses a group of reactions in organic chemistry in which two radicals react to form two different non-radical products. Radicals in chemistry are defined as reactive atoms or molecules that contain an unpaired electron or electrons in an open shell. The unpaired electrons can cause radicals to be unstable and ...
Radicals can undergo a disproportionation reaction through a radical elimination mechanism (See Fig. 1). Here a radical abstracts a hydrogen atom from another same radical to form two non-radical species: an alkane and an alkene. Radicals can also undergo an elimination reaction to generate a new radical as the leaving group.
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
A solution in radicals or algebraic solution is an expression of a solution of a polynomial equation that is algebraic, that is, relies only on addition, subtraction, multiplication, division, raising to integer powers, and extraction of n th roots (square roots, cube roots, etc.). A well-known example is the quadratic formula
An unresolved root, especially one using the radical symbol, is sometimes referred to as a surd [2] or a radical. [3] Any expression containing a radical, whether it is a square root, a cube root, or a higher root, is called a radical expression , and if it contains no transcendental functions or transcendental numbers it is called an algebraic ...
This meant a solution in radicals, that is, an expression involving only the coefficients of the equation, and the operations of addition, subtraction, multiplication, division, and n th root extraction.
The symbol was first seen in print without the vinculum (the horizontal "bar" over the numbers inside the radical symbol) in the year 1525 in Die Coss by Christoff Rudolff, a German mathematician. In 1637 Descartes was the first to unite the German radical sign √ with the vinculum to create the radical symbol in common use today. [3]