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Other examples of inorganic polyprotic acids include anions of sulfuric acid, phosphoric acid and hydrogen sulfide that have lost one or more protons. In organic chemistry and biochemistry, important examples include amino acids and derivatives of citric acid. Although an amphiprotic species must be amphoteric, the converse is not true.
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula H 2 SO 4. It is a colorless, odorless, and viscous liquid that is miscible with water. [6] Structure ...
For example, aqueous perchloric acid (HClO 4), aqueous hydrochloric acid (HCl) and aqueous nitric acid (HNO 3) are all completely ionized, and are all equally strong acids. [3] Similarly, when ammonia is the solvent, the strongest acid is ammonium (NH 4 +), thus HCl and a super acid exert the same acidifying effect. The same argument applies to ...
Deprotonation of acetic acid by a hydroxide ion. Deprotonation (or dehydronation) is the removal (transfer) of a proton (or hydron, or hydrogen cation), (H +) from a Brønsted–Lowry acid in an acid–base reaction. [1] [2] The species formed is the conjugate base of that acid.
An acid which has more of a tendency to donate a hydrogen ion than the limiting acid will be a strong acid in the solvent considered, and will exist mostly or entirely in its dissociated form. Likewise, the limiting base in a given solvent is the solvate ion, such as OH - ( hydroxide ) ion, in water.
This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent conditions. This is apparent in the ΔE a, ΔΔG ‡ activation. On the right is an S N 2 reaction coordinate diagram. Note the decreased ΔG ‡ activation for the non-polar-solvent reaction ...
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An amino acid is also amphoteric with the added complication that the neutral molecule is subject to an internal acid–base equilibrium in which the basic amino group attracts and binds the proton from the acidic carboxyl group, forming a zwitterion.