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More generally, the term cross-section is used in physics to quantify the probability of a certain particle-particle interaction, e.g., scattering, electromagnetic absorption, etc. (Note that light in this context is described as consisting of particles, i.e., photons.) A typical absorption cross-section has units of cm 2 ⋅molecule −1.
The absorption coefficient is fundamentally the product of a quantity of absorbers per unit volume, [cm −3], times an efficiency of absorption (area/absorber, [cm 2]). Several sources [2] [12] [3] replace nσ λ with k λ r, where k λ is the absorption coefficient per unit density and r is the density of the gas.
In physics, the cross section is a measure of the probability that a specific process will take place in a collision of two particles. For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during an interaction with an atomic nucleus.
The mass attenuation coefficient (also called "mass extinction coefficient"), which is the absorption coefficient divided by density; The absorption cross section and scattering cross-section, related closely to the absorption and attenuation coefficients, respectively "Extinction" in astronomy, which is equivalent to the attenuation coefficient
To describe the attenuation coefficient in a way independent of the number densities n i of the N attenuating species of the material sample, one introduces the attenuation cross section = (). σ i has the dimension of an area; it expresses the likelihood of interaction between the particles of the beam and the particles of the species i in the ...
This scattering length varies by isotope (and by element as the weighted arithmetic mean over the constituent isotopes) in a way that appears random, whereas the X-ray scattering length is just the product of atomic number and Thomson scattering length, thus monotonically increasing with atomic number. [1] [2]
The cross section obtained in this way is called the total cross section and is usually denoted by a σ or σ T. Typical nuclear radii are of the order 10 −15 m. Assuming spherical shape, we therefore expect the cross sections for nuclear reactions to be of the order of π r 2 {\displaystyle \pi r^{2}} or 10 −28 m 2 (i.e., 1 barn).
X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]