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The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
The process of photosynthesis provides the main input of free energy into the biosphere, and is one of four main ways in which radiation is important for plant life. [115] The radiation climate within plant communities is extremely variable, in both time and space.
The free energy created is then used, via a chain of nearby electron acceptors, for a transfer of hydrogen atoms (as protons and electrons) from H 2 O or hydrogen sulfide towards carbon dioxide, eventually producing glucose. These electron transfer steps ultimately result in the conversion of the energy of photons to chemical energy.
The high-energy oxidized tyrosine gives off its energy and returns to the ground state by taking up a proton and removing an electron from the oxygen-evolving complex and ultimately from water. [4] Kok's S-state diagram shows the reactions of water splitting in the oxygen-evolving complex.
The activation energy for the reaction is typically larger than the overall energy of the exergonic reaction (1). Endergonic reactions are nonspontaneous. The progress of the reaction is shown by the line. The change of Gibbs free energy (ΔG) during an endergonic reaction is a positive value because energy is gained (2).
Beginning with photosynthesis, water (blue) and carbon dioxide (white) from the air are taken in with solar energy (yellow), and are converted into plant energy (green). [7] 100×10 15 grams of carbon/year fixed by photosynthetic organisms, which is equivalent to 4×10 18 kJ/yr = 4×10 21 J/yr of free energy.
Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i.e., work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [1]
A simplified diagram of photosynthesis. Redrawn in vector format from Image:Simple_photosynthesis_overview.PNG: Date: 18 April 2008: Source: Own work: Author: Daniel Mayer (mav) - original image Vector version by Yerpo: Other versions
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