Search results
Results from the WOW.Com Content Network
The process of chemical reaction can be considered as involving the diffusion of reactants until they encounter each other in the right stoichiometry and form an activated complex which can form the product species. The observed rate of chemical reactions is, generally speaking, the rate of the slowest or "rate determining" step.
Another example is the unimolecular nucleophilic substitution (S N 1) reaction in organic chemistry, where it is the first, rate-determining step that is unimolecular. A specific case is the basic hydrolysis of tert-butyl bromide (t-C 4 H 9 Br) by aqueous sodium hydroxide. The mechanism has two steps (where R denotes the tert-butyl radical t-C ...
Diffusion limited perfect enzymes are very rare. Most enzymes catalyse their reactions to a rate that is 1,000-10,000 times slower than this limit. This is due to both the chemical limitations of difficult reactions, and the evolutionary limitations that such high reaction rates do not confer any extra fitness. [1]
It is a limit point of the class of ordinal numbers, with respect to the order topology. (The other ordinals are isolated points.) Some contention exists on whether or not 0 should be classified as a limit ordinal, as it does not have an immediate predecessor; some textbooks include 0 in the class of limit ordinals [1] while others exclude it. [2]
Examples abound, one of the simplest being that for a double sequence a m,n: it is not necessarily the case that the operations of taking the limits as m → ∞ and as n → ∞ can be freely interchanged. [4] For example take a m,n = 2 m − n. in which taking the limit first with respect to n gives 0, and with respect to m gives ∞.
An example of an order parameter for crystallization is "bond orientational order" describing the development of preferred directions (the crystallographic axes) in space. For many systems, phases with more structural (e.g. crystalline) order exhibit less entropy than fluid phases under the same thermodynamic conditions.
Equilibrium chemistry is concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero.
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...