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Thallium, then, like its congeners, is a soft, highly electrically conducting metal with a low melting point, of 304 °C. [ 11 ] A number of standard electrode potentials, depending on the reaction under study, [ 12 ] are reported for thallium, reflecting the greatly decreased stability of the +3 oxidation state: [ 11 ]
Normal background blood and urine concentrations in healthy persons are usually less than 1 μg/litre, but they are often in the 1–10 mg/litre range (1,000–10,000 times higher) in survivors of acute intoxication. [10] [11] Thallium is present in the blood for a very short time so urine testing is usually most appropriate. A quick way to ...
Thallium(I) sulfate is soluble in water and its toxic effects are derived from the thallium(I) cation. The mean lethal dose of thallium(I) sulfate for an adult is about 1 gram. Since thallium(I) sulfate is a simple powder with indistinctive properties, it can easily be mistaken for more innocuous chemicals.
A flame test involves introducing a sample of the element or compound to a hot, non-luminous flame and observing the color of the flame that results. [4] The compound can be made into a paste with concentrated hydrochloric acid, as metal halides, being volatile, give better results. [5] Different flames can be tried to verify the accuracy of ...
Instead of the green thallium lines that he expected, he saw a new line of deep indigo-blue. Concluding that it must come from a new element, they named it after the characteristic indigo color it had produced. [29] [31] Gallium minerals were not known before August 1875, when the element itself was discovered.
Thallium(I) iodide has the CsCl crystal structure. The monohalides, also known as thallous halides, all contain thallium with oxidation state +1. Parallels can be drawn between the thallium(I) halides and their corresponding silver salts; for example, thallium(I) chloride and bromide are light-sensitive, and thallium(I) fluoride is more soluble in water than the chloride and bromide.
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Example thallide monoclinic Cs 7.29 K 5.71 Tl 13 containing [Tl 6] 6− and [Tl 7] 7− clusters. Thallides are compounds containing anions composed of thallium.There are several thallium atoms in a cluster, and it does not occur as a single Tl − in thallides.