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Ethyl acrylate is produced by acid-catalysed esterification of acrylic acid, which in turn is produced by oxidation of propylene. It may also be prepared from acetylene, carbon monoxide and ethanol by a Reppe reaction. Commercial preparations contain a polymerization inhibitor such as hydroquinone, phenothiazine, or hydroquinone ethyl ether. [5]
Acrylic acid was once manufactured by the hydrolysis of acrylonitrile, a material derived from propene by ammoxidation, but this route was abandoned because it cogenerates ammonium side products, which must be disposed of. Other now abandoned precursors to acrylic acid include ethenone and ethylene cyanohydrin. [7]
Acrylic elastomer is a general term for a type of synthetic rubber whose primary component is acrylic acid alkyl ester (ethyl or butyl ester). [3] Acrylic elastomer possesses characteristics of heat and oil resistance, with the ability to withstand temperatures of 170–180 °C. It is used primarily for producing oil seals and packaging related ...
Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid. The acrylate ion is the anion CH 2 =CHCO − 2. Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate. These acrylates contain vinyl groups.
Polyacrylic acid is a weak anionic polyelectrolyte, whose degree of ionisation is dependent on solution pH. In its non-ionised form at low pHs, PAA may associate with various non-ionic polymers (such as polyethylene oxide, poly-N-vinyl pyrrolidone, polyacrylamide, and some cellulose ethers) and form hydrogen-bonded interpolymer complexes. [17]
Recycling codes on products. Recycling codes are used to identify the materials out of which the item is made, to facilitate easier recycling process.The presence on an item of a recycling code, a chasing arrows logo, or a resin code, is not an automatic indicator that a material is recyclable; it is an explanation of what the item is made of.
Copolymer of ethylene and unsaturated carboxylic acids (such as acrylic acid) are characterized by good adhesion to diverse materials, by resistance to stress cracking and high flexibility. [40] However, they are more sensitive to heat and oxidation than ethylene homopolymers. Ethylene/acrylic acid copolymers are used as adhesion promoters. [19]
Ethylene has long represented the major nonfermentative precursor to ethanol. The original method entailed its conversion to diethyl sulfate, followed by hydrolysis. The main method practiced since the mid-1990s is the direct hydration of ethylene catalyzed by solid acid catalysts: [18] C 2 H 4 + H 2 O → CH 3 CH 2 OH