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The first crystalline silicic acid was prepared from the phyllosilicate natrosilite (Na 2 Si 2 O 5) in 1924. More than 15 crystalline acids are known and comprise at least six modifications of H 2 Si 2 O 5. Some acids can adsorb and intercalate organic molecules, and therefore are interesting alternatives to silica. [10]
In dimeric silicon dioxide there are two oxygen atoms bridging between the silicon atoms with an Si–O–Si angle of 94° and bond length of 164.6 pm and the terminal Si–O bond length is 150.2 pm. The Si–O bond length is 148.3 pm, which compares with the length of 161 pm in α-quartz. The bond energy is estimated at 621.7 kJ/mol. [21]
The exhibited hydrophobicity is a result of the chemical reaction occurring between the silica particles and the TMCS. When the original SiO 2-OH groups are replaced with hydrolytically stable Si(CH 3) groups, this hydrophobicity occurs due to the prevention of the silica particles from interacting with water. [8]
Silicon compounds are compounds containing the element silicon (Si). As a carbon group element, silicon often forms compounds in the +4 oxidation state, though many unusual compounds have been discovered that differ from expectations based on its valence electrons, including the silicides and some silanes.
Alternative depiction of a metasilicate chain emphasizing the Si-O bonds. With two shared oxides bound to each silicon, cyclic or polymeric structures can result. The cyclic metasilicate ring Si 6 O 12− 18 is a hexamer of SiO 3 2-. Polymeric silicate anions of can exist also as long chains.
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Again there is variation in composition: magnesium silicide is represented by Mg 2 Si, [9] calcium silicide can be represented by Ca 2 Si, CaSi, CaSi 2, Ca 5 Si 3 and by Ca 14 Si 19, [10] strontium silicide can be represented by Sr 2 Si, SrSi 2 and Sr 5 Si 3 [11] and barium silicide can be represented by Ba 2 Si, BaSi 2, Ba 5 Si 3 and Ba 3 Si 4 ...
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