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They display quantum confinement in that the electrons cannot escape the “dot”, thus allowing particle-in-a-box approximations to be used. [23] Their behavior can be described by three-dimensional particle-in-a-box energy quantization equations. [23] The energy gap of a quantum dot is the energy gap between its valence and conduction bands.
Maxwell's equations are the basis of theoretical and computational methods describing light scattering, but since exact solutions to Maxwell's equations are only known for selected particle geometries (such as spherical), light scattering by particles is a branch of computational electromagnetics dealing with electromagnetic radiation ...
A rectangular box (such as a box of breakfast cereal) or cylinder (such as a can of nuts) works well to favour the effect, [citation needed] while a container with outwardly slanting walls (such as in a conical or spherical geometry) results in what is known as the reverse Brazil nut effect.
A quasiparticle is usually thought of as being like a dressed particle: it is built around a real particle at its "core", but the behavior of the particle is affected by the environment. A standard example is the "electron quasiparticle": an electron in a crystal behaves as if it had an effective mass which differs from its real mass.
In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. [ 1 ] [ 2 ] They vary greatly in size or quantity, from subatomic particles like the electron , to microscopic particles like atoms and molecules ...
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The size of the simulation box must also be large enough to prevent periodic artifacts from occurring due to the unphysical topology of the simulation. In a box that is too small, a macromolecule may interact with its own image in a neighboring box, which is functionally equivalent to a molecule's "head" interacting with its own "tail".
When talking about solid materials, the discussion is mainly around crystals – periodic lattices. Here we will discuss a 1D lattice of positive ions. Assuming the spacing between two ions is a, the potential in the lattice will look something like this: The mathematical representation of the potential is a periodic function with a period a.