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David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition, online version. CRC Press. Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Vapor Pressure of the Metallic Elements The equations reproduce the observed pressures to an accuracy of ±5% or better. Coefficients from this source:
This is illustrated in the vapor pressure chart (see right) that shows graphs of the vapor pressures versus temperatures for a variety of liquids. [7] At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [1] 760 Torr, 101.325 kPa, or 14.69595 psi.
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
p is the pressure; V is the volume; n is the amount of substance of gas (moles) R is the gas constant, 8.314 J·K −1 mol −1; T is the absolute temperature; To simplify, a volume of gas may be expressed as the volume it would have in standard conditions for temperature and pressure, which are 0 °C (32 °F) and 100 kPa. [2]
ρ of vapor Δ vap H: The table above gives properties of the vapor–liquid equilibrium of anhydrous ammonia at various temperatures. The second column is vapor pressure in kPa. The third column is the density of the liquid phase. The fourth column is the density of the vapor. The fifth column is the heat of vaporization needed to convert one ...
Vapor pressure of liquid ... 210.8: 250.0 — Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. log 10 of n-propanol vapor pressure. Uses ...