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  2. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    According to VSEPR theory, diethyl ether, methanol, water and oxygen difluoride should all have a bond angle of 109.5 o. [12] Using VSEPR theory, all these molecules should have the same bond angle because they have the same "bent" shape. [12] Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in ...

  3. Ether - Wikipedia

    en.wikipedia.org/wiki/Ether

    In organic chemistry, ethers are a class of compounds that contain an ether group—a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl). They have the general formula R−O−R′ , where R and R′ represent the organyl groups.

  4. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecular geometries can be specified in terms of 'bond lengths', 'bond angles' and 'torsional angles'. The bond length is defined to be the average distance between the nuclei of two atoms bonded together in any given molecule. A bond angle is the angle formed between three atoms across at least two bonds.

  5. Walsh diagram - Wikipedia

    en.wikipedia.org/wiki/Walsh_diagram

    Walsh Diagram of an HAH molecule. Walsh diagrams, often called angular coordinate diagrams or correlation diagrams, are representations of calculated orbital binding energies of a molecule versus a distortion coordinate (bond angles), used for making quick predictions about the geometries of small molecules.

  6. Alkoxy group - Wikipedia

    en.wikipedia.org/wiki/Alkoxy_group

    In chemistry, the alkoxy group is an alkyl group which is singularly bonded to oxygen; thus R−O. Denoted usually with apostrophe('). The range of alkoxy groups is vast, the simplest being methoxy (CH 3 O−). [1] An ethoxy group (CH 3 CH 2 O−) is found in the organic compound ethyl phenyl ether (C 6 H 5 OCH 2 CH 3, also known as ethoxybenzene).

  7. Ball-and-stick model - Wikipedia

    en.wikipedia.org/wiki/Ball-and-stick_model

    In chemistry, the ball-and-stick model is a molecular model of a chemical substance which displays both the three-dimensional position of the atoms and the bonds between them. [1] The atoms are typically represented by spheres , connected by rods which represent the bonds.

  8. Orbital overlap - Wikipedia

    en.wikipedia.org/wiki/Orbital_overlap

    Orbital overlap can lead to bond formation. The general principle for orbital overlap is that, the greater the greater the over between orbitals, the greater is the bond strength. Linus Pauling explained the importance of orbital overlap in the molecular bond angles observed through experimentation; it is the basis for orbital hybridization.

  9. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos (− ⁠ 1 / 3 ⁠ ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane ( CH 4 ) [ 1 ] [ 2 ] as well as its heavier analogues .