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  2. Atom transfer radical polymerization - Wikipedia

    en.wikipedia.org/wiki/Atom_Transfer_Radical...

    The K ATRP value depends on the homo-cleavage energy of the alkyl halide and the redox potential of the Cu catalyst with different ligands. Given two alkyl halides (R 1-X and R 2-X) and two ligands (L 1 and L 2), there will be four combinations between different alkyl halides and ligands. Let K ij ATRP refer to the K ATRP value for R i-X and L ...

  3. Copper-based reversible-deactivation radical polymerization

    en.wikipedia.org/wiki/Copper-based_reversible...

    Although copper complexes (in combination with relevant ligands) have long been used as catalysts for organic reactions such as atom transfer radical addition (ATRA) and copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC), copper complex catalyzed RDRP was not reported until 1995 when Jin-Shan Wang and Krzysztof Matyjaszewski introduced it as atom transfer radical polymerization (ATRP).

  4. Krzysztof Matyjaszewski - Wikipedia

    en.wikipedia.org/wiki/Krzysztof_Matyjaszewski

    Krzysztof "Kris" Matyjaszewski (Polish: [ˈkʂɨʂtɔf matɨjaˈʂɛfskʲi]; born April 8, 1950) is a Polish-American [1] chemist.He is the J.C. Warner Professor of the Natural Sciences at the Carnegie Mellon University [2] Matyjaszewski is best known for the discovery of atom transfer radical polymerization (ATRP), a novel method of polymer synthesis that has revolutionized the way ...

  5. Reversible-deactivation radical polymerization - Wikipedia

    en.wikipedia.org/wiki/Reversible-deactivation...

    There is a mode of polymerization referred to as reversible-deactivation polymerization which is distinct from living polymerization, despite some common features. Living polymerization requires a complete absence of termination reactions, whereas reversible-deactivation polymerization may contain a similar fraction of termination as conventional polymerization with the same concentration of ...

  6. ATRP - Wikipedia

    en.wikipedia.org/wiki/ATRP

    This page was last edited on 27 December 2019, at 18:18 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.

  7. Reversible addition−fragmentation chain-transfer polymerization

    en.wikipedia.org/wiki/Reversible_addition%E2%88...

    RAFT polymerization today is mainly carried out by thiocarbonylthio chain transfer agents. It was first reported by Rizzardo et al. in 1998. [6] RAFT is one of the most versatile methods of controlled radical polymerization because it is tolerant of a very wide range of functionality in the monomer and solvent, including aqueous solutions. [7]

  8. Living free-radical polymerization - Wikipedia

    en.wikipedia.org/wiki/Living_free-radical...

    Living free radical polymerization is a type of living polymerization where the active polymer chain end is a free radical.Several methods exist. IUPAC recommends [1] to use the term "reversible-deactivation radical polymerization" instead of "living free radical polymerization", though the two terms are not synonymous.

  9. GTRI Agricultural Technology Research Program - Wikipedia

    en.wikipedia.org/wiki/GTRI_Agricultural...

    The Agricultural Technology Research Program (ATRP) is part of the Aerospace, Transportation and Advanced Systems Laboratory of the Georgia Tech Research Institute. It was founded in 1973 to work with Georgia agribusiness , especially the poultry industry, to develop new technologies and adapt existing ones for specialized industrial needs. [ 1 ]