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To reduce the concentration of Pu-240 in the plutonium produced, weapons program plutonium production reactors (e.g. B Reactor) irradiate the uranium for a far shorter time than is normal for a nuclear power reactor. More precisely, weapons-grade plutonium is obtained from uranium irradiated to a low burnup.
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Plutonium(IV) oxide, or plutonia, is a chemical compound with the formula Pu O 2. This high melting-point solid is a principal compound of plutonium . It can vary in color from yellow to olive green, depending on the particle size, temperature and method of production.
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A small percentage of plutonium-239 can be deliberately added to fresh nuclear fuel. Such fuel is called MOX (mixed oxide) fuel, as it contains a mixture of uranium dioxide (UO 2) and plutonium dioxide (PuO 2). The addition of plutonium-239 reduces the need to enrich the uranium in the fuel.
It is the acid anion that influences the degree of complexing—how atoms connect to a central atom—of the plutonium species. Additionally, the formal +2 oxidation state of plutonium is known in the complex [K(2.2.2-cryptand)] [Pu II Cp″ 3], Cp″ = C 5 H 3 (SiMe 3) 2. [5] A +8 oxidation state is possible as well in the volatile tetroxide ...
Plutonium hexafluoride is the highest fluoride of plutonium, and is of interest for laser enrichment of plutonium, in particular for the production of pure plutonium-239 from irradiated uranium. This isotope of plutonium is needed to avoid premature ignition of low-mass nuclear weapon designs by neutrons produced by spontaneous fission of ...
Plutonium oxide is substantially more toxic than uranium oxide, making fuel manufacture more difficult and expensive. As plutonium isotopes absorb more neutrons than uranium fuels, reactor control systems may need modification. MOX fuel tends to run hotter because of lower thermal conductivity, which may be an issue in some reactor designs.