Search results
Results from the WOW.Com Content Network
The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential.
Standard electrode potential (data page) The data below tabulates standard electrode potentials (E °), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent ...
Appearance. Redox potential (also known as oxidation / reduction potential, ORP, pe, , or ) is a measure of the tendency of a chemical species to acquire electrons from or lose electrons to an electrode and thereby be reduced or oxidised respectively. Redox potential is expressed in volts (V). Each species has its own intrinsic redox potential ...
The hydrogen electrode is based on the redox half cell corresponding to the reduction of two hydrated protons, 2H+(aq), into one gaseous hydrogen molecule, H2 (g). General equation for a reduction reaction: The reaction quotient (Qr) of the half-reaction is the ratio between the chemical activities (a) of the reduced form (the reductant, ared ...
A reference electrode is an electrode that has a stable and well-known electrode potential. The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode, the reference electrode is standardized with ...
Electrode potential. In electrochemistry, electrode potential is the voltage of a galvanic cell built from a standard reference electrode and another electrode to be characterized. [1] By convention, the reference electrode is the standard hydrogen electrode (SHE). It is defined to have a potential of zero volts.
Application. Latimer diagrams can be used in the construction of Frost diagrams, as a concise summary of the standard electrode potentials relative to the element. Since ΔrG o = -n F E o, the electrode potential is a representation of the Gibbs energy change for the given reduction. The sum of the Gibbs energy changes for subsequent reductions ...
Where is the standard reduction potential of the half-reaction expressed versus the standard reduction potential of hydrogen. For standard conditions in electrochemistry (T = 25 °C, P = 1 atm and all concentrations being fixed at 1 mol/L, or 1 M) the standard reduction potential of hydrogen is fixed at zero by convention as it serves of reference.