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The concentration of the solution can be determined by knowing the number of particles present in it, which can be done by determining the freezing point of the solution. When particles are dissolved in a solution, their freezing point is lowered compared to that of the original solvent. A further increase in the solute decreases the freezing ...
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid: 298.9 44 ...
The freezing point is the temperature at which the liquid solvent and solid solvent are at equilibrium, so that their vapor pressures are equal. When a non-volatile solute is added to a volatile liquid solvent, the solution vapour pressure will be lower than that of the pure solvent.
The van 't Hoff factor i (named after Dutch chemist Jacobus Henricus van 't Hoff) is a measure of the effect of a solute on colligative properties such as osmotic pressure, relative lowering in vapor pressure, boiling-point elevation and freezing-point depression.
Freezing point depression and boiling point elevation. In chemistry, colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present. [1]
The laboratory value measures the freezing point depression, properly called osmolality while the calculated value is given in units of osmolarity. Even though these values are presented in different units, when there is a small amount of solute compared to total volume of solution, the absolute values of osmolality vs. osmolarity are very close.
See also "Typical Freezing and Boiling Points of Aqueous Solutions of DOWTHERM SR-1 and DOWTHERM-SR4000" (PDF). Dow Chemical. Dow Chemical. Archived from the original (PDF) on 27 September 2007 .
The cloud point of a nonionic surfactant or glycol solution is the temperature at which the mixture starts to phase-separate, and two phases appear, thus becoming cloudy. This behavior is characteristic of non-ionic surfactants containing polyoxyethylene chains, which exhibit reverse solubility versus temperature behavior in water and therefore ...