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A halogen addition reaction is a simple organic reaction where a halogen molecule is added to the carbon–carbon double bond of an alkene functional group. [1] The general chemical formula of the halogen addition reaction is: C=C + X 2 → X−C−C−X (X represents the halogens bromine or chlorine, and in this case, a solvent could be CH 2 ...
The addition of halogens to alkenes proceeds via intermediate halonium ions. In special cases, such intermediates have been isolated. [5] Bromination is more selective than chlorination because the reaction is less exothermic. Illustrative of the bromination of an alkene is the route to the anesthetic halothane from trichloroethylene: [6]
Halohydrins are usually prepared by treatment of an alkene with a halogen, in the presence of water. The reaction is a form of electrophilic addition, with the halogen acting as electrophile. [2] In that regard, it resembles the halogen addition reaction and proceeds with anti addition, leaving the newly added X and OH groups in a trans ...
Similarly, halogenation involves the addition of a halogen molecule, such as Br 2, resulting in a dihaloalkane. The equation of bromination of ethylene to form ethane is: H 2 C=CH 2 + Br 2 →H 2 CBr−CH 2 Br. Unlike hydrogenation, these halogenation reactions do not require catalysts. The reaction occurs in two steps, with a halonium ion as ...
A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...
Removal of a halogen atom from an organohalide generates a radical. Such reactions are difficult to achieve and, when they can be achieved, these processes often lead to complicated mixtures. When a pair of halides are mutually adjacent , their removal is favored. Such reactions give alkenes in the case of vicinal alkyl dihalides: [2]
Alkenes also react with halogens (X 2) to form haloalkanes with two neighboring halogen atoms in a halogen addition reaction. Alkynes react similarly, forming the tetrahalo compounds. This is sometimes known as "decolorizing" the halogen, since the reagent X 2 is colored and the product is usually colorless and odorless. [citation needed]
This reaction is considered Markovnikov because the halogen substituent attaches to the more substituted carbon. Hydration: Can occur either in syn or anti addition fashion, depending on the solution it is in; 50% of each orientation. This reaction is considered Markovnikov because the hydroxyl group attaches to the more substituted carbon.