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If the concentration of a reactant remains constant (because it is a catalyst, or because it is in great excess with respect to the other reactants), its concentration can be included in the rate constant, leading to a pseudo–first-order (or occasionally pseudo–second-order) rate equation. For a typical second-order reaction with rate ...
For example, the second-order equation y′′ = −y can be rewritten as two first-order equations: y′ = z and z′ = −y. In this section, we describe numerical methods for IVPs, and remark that boundary value problems (BVPs) require a different set of tools. In a BVP, one defines values, or components of the solution y at more than one ...
In fact, however, the observed reaction rate is second-order in NO 2 and zero-order in CO, [5] with rate equation r = k[NO 2] 2. This suggests that the rate is determined by a step in which two NO 2 molecules react, with the CO molecule entering at another, faster, step. A possible mechanism in two elementary steps that explains the rate ...
You can add a table using HTML rather than wiki markup, as described at HTML element#Tables. However, HTML tables are discouraged because wikitables are easier to customize and maintain, as described at manual of style on tables. Also, note that the <thead>, <tbody>, <tfoot>, <colgroup>, and <col> elements are not supported in wikitext.
Plugging in the first CSTR equation to the second: = (+) Therefore for m identical CSTRs in series: C A m = C A o ( 1 + k τ ) m {\displaystyle C_{Am}={\frac {C_{Ao}}{(1+k\tau )^{m}}}} When the volumes of the individual CSTRs in series vary, the order of the CSTRs does not change the overall conversion for a first order reaction as long as the ...
Then the Thiele modulus for a first order reaction is: = From this relation it is evident that with large values of , the rate term dominates and the reaction is fast, while slow diffusion limits the overall rate. Smaller values of the Thiele modulus represent slow reactions with fast diffusion.
See Template:Date table sorting for more info. In the tables below, all columns sort correctly. The wikitext for the first entry in each table in the first row is shown in the table header. Note: None of the table columns use the data-sort-type= modifier. Using data-sort-type= can sometimes break sorting when used with the template.
Given a simply connected and open subset D of and two functions I and J which are continuous on D, an implicit first-order ordinary differential equation of the form (,) + (,) =,is called an exact differential equation if there exists a continuously differentiable function F, called the potential function, [1] [2] so that