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A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. Thus a prism of 1 Δ would produce 1 cm visible displacement at 100 cm, or 1 metre. This can be represented mathematically as: = where is the amount of prism correction in prism dioptres, and is the angle of deviation of the light.
The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel. It describes how the electrical current ...
Hückel method. The Hückel method or Hückel molecular orbital theory, proposed by Erich Hückel in 1930, is a simple method for calculating molecular orbitals as linear combinations of atomic orbitals. The theory predicts the molecular orbitals for π-electrons in π-delocalized molecules, such as ethylene, benzene, butadiene, and pyridine.
Scherrer equation. The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub- micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis. It is named after Paul Scherrer.
The Stern–Volmer relationship, named after Otto Stern and Max Volmer, [1] allows the kinetics of a photophysical intermolecular deactivation process to be explored. Processes such as fluorescence and phosphorescence are examples of intramolecular deactivation ( quenching) processes. An intermolecular deactivation is where the presence of ...
For Faraday's first law, W, F, v are constants; thus, the larger the value of Q, the larger W will be. For Faraday's second law, Q, F, v are constants; thus, the larger the value of (equivalent weight), the larger W will be. In the simple case of constant- current electrolysis, Q = It, leading to. and then to. where: t is the total time the ...
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right ...
In thermodynamics, the Volume Correction Factor (VCF), also known as Correction for the effect of Temperature on Liquid (CTL), is a standardized computed factor used to correct for the thermal expansion of fluids, primarily, liquid hydrocarbons at various temperatures and densities. [1] [2] It is typically a number between 0 and 2, rounded to ...