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Carothers equation. In step-growth polymerization, the Carothers equation (or Carothers' equation) gives the degree of polymerization, Xn, for a given fractional monomer conversion, p. There are several versions of this equation, proposed by Wallace Carothers, who invented nylon in 1935.
For Regime I, the growth rate on the front laterally, referred to as g, is the rate-determining step (RDS) and exceeds the secondary nucleation rate, i. In this instance of g >> i , monolayers are formed one at a time so that if the substrate has a length of L p and thickness, b , the overall linear growth can be described through the equation
RGR is a concept relevant in cases where the increase in a state variable over time is proportional to the value of that state variable at the beginning of a time period. In terms of differential equations, if is the current size, and its growth rate, then relative growth rate is. . If the RGR is constant, i.e., , a solution to this equation is.
Exponential growth is a process that increases quantity over time at an ever-increasing rate. It occurs when the instantaneous rate of change (that is, the derivative) of a quantity with respect to time is proportional to the quantity itself. Described as a function, a quantity undergoing exponential growth is an exponential function of time ...
Doubling time. The doubling time is the time it takes for a population to double in size/value. It is applied to population growth, inflation, resource extraction, consumption of goods, compound interest, the volume of malignant tumours, and many other things that tend to grow over time. When the relative growth rate (not the absolute growth ...
The Gompertz curve or Gompertz function is a type of mathematical model for a time series, named after Benjamin Gompertz (1779–1865). It is a sigmoid function which describes growth as being slowest at the start and end of a given time period. The right-side or future value asymptote of the function is approached much more gradually by the ...
The Paris–Erdogan equation fits the central linear region of Regime B. A crack growth equation is used for calculating the size of a fatigue crack growing from cyclic loads. The growth of a fatigue crack can result in catastrophic failure, particularly in the case of aircraft. When many growing fatigue cracks interact with one another it is ...
The model was first published in 1965 by Bruce Deal and Andrew Grove of Fairchild Semiconductor, [1] building on Mohamed M. Atalla 's work on silicon surface passivation by thermal oxidation at Bell Labs in the late 1950s. [2] This served as a step in the development of CMOS devices and the fabrication of integrated circuits.