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Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
Ruddlesden-Popper (RP) phases are a type of perovskite structure that consists of two-dimensional perovskite-like slabs interleaved with cations.The general formula of an RP phase is A n+1 B n X 3n+1, where A and B are cations, X is an anion (e.g., oxygen), and n is the number of octahedral layers in the perovskite-like stack. [1]
Crystal structure of CH 3 NH 3 PbX 3 perovskites (X=I, Br and/or Cl). The methylammonium cation (CH 3 NH 3 +) is surrounded by PbX 6 octahedra. [13]The name "perovskite solar cell" is derived from the ABX 3 crystal structure of the absorber materials, referred to as perovskite structure, where A and B are cations and X is an anion.
A perovskite is a crystalline material of formula ABX 3 with a crystal structure similar to that of the mineral perovskite, this latter consisting of calcium titanium oxide (CaTiO 3). [2] The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856).
Aurivillius phases are a form of perovskite represented by the general formulae is (Bi 2 O 2)(A n−1 B n O 3n+1) (where A is a large 12 co-ordinate cation, and B is a small 6 co-ordinate cation).
In general, the perovskite nanocrystal surface is considered to be both ionic and highly dynamic. However, the ionic properties caused the instability of perovskite nanocrystals in humid condition and the degradation process can be accelerated by photoirradiation, which can alter the electronic properties of nanocrystals. [128]
Methylammonium lead halides (MALHs) are solid compounds with perovskite structure and a chemical formula of [CH 3 NH 3] + Pb 2+ (X −) 3, where X = Cl, Br or I. They have potential applications in solar cells, [2] lasers, light-emitting diodes, photodetectors, radiation detectors, [3] [4] scintillator, [5] magneto-optical data storage [6] and ...
Its properties may be modified by doping it with lanthanum, resulting in lanthanum-doped lead zirconium titanate (lead zirconate titanate, also called lead lanthanum zirconium titanate), with formula Pb 0.83 La 0.17 (Zr 0.3 Ti 0.7) 0.9575 O 3 (lead zirconate titanate 17/30/70). [12] [13]