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The usual atomic term symbols assume LS coupling (also known as Russell–Saunders coupling), in which the atom's total spin quantum number S and the total orbital angular momentum quantum number L are "good quantum numbers". (Russell–Saunders coupling is named after Henry Norris Russell and Frederick Albert Saunders, who described it in 1925 ...
Term symbols are used to represent the states and spectral transitions of atoms, they are found from coupling of angular momenta mentioned above. When the state of an atom has been specified with a term symbol, the allowed transitions can be found through selection rules by considering which transitions would conserve angular momentum .
We need to consider only the outer 3p 2 electrons, for which it can be shown (see term symbols) that the possible terms allowed by the Pauli exclusion principle are 1 D , 3 P , and 1 S. Hund's first rule now states that the ground state term is 3 P, which has S = 1. The superscript 3 is the value of the multiplicity = 2S + 1 = 3.
Henry Norris Russell ForMemRS HFRSE FRAS (October 25, 1877 – February 18, 1957) was an American astronomer who, along with Ejnar Hertzsprung, developed the Hertzsprung–Russell diagram (1910). In 1923, working with Frederick Saunders , he developed Russell–Saunders coupling, which is also known as LS coupling .
For further clarification on the notation refer to the article on the Russell–Saunders term symbol. For nuclei farther from the magic quantum numbers one must add the assumption that due to the relation between the strong nuclear force and total angular momentum, protons or neutrons with the same n tend to form pairs of opposite angular momentum.
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This notation is used to specify electron configurations and to create the term symbol for the electron states in a multi-electron atom. When writing a term symbol, the above scheme for a single electron's orbital quantum number is applied to the total orbital angular momentum associated to an electron state. [4]
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